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Why Solids Expand

15 min read4 ideas8 checks2 figures to playBy Asheshanand Acharya
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Why solids expand
Look around
The gap at the rail joint

Stand on a railway platform in Rajasthan and look along an older track. Every thirteen metres two rails meet at a joint held by a steel plate, and a small gap is left between them. In a January dawn the gap is a few millimetres wide. On a May afternoon it has almost closed. The wheels click at every gap.

you will calculate how wide the gap at a rail joint must be for a Rajasthan summer, and see why one gap serves two rails.

A lopsided pull

A solid is a crowd of atoms held in place by forces between neighbours. Push two atoms closer and they repel strongly. Pull them apart and they attract, but the pull weakens slowly with distance. The potential energy of a pair against their separation is therefore a lopsided well. It is steep on the near side and gentle on the far side.

Each atom vibrates in this well. You met such wells in the chapter on energy. A particle with energy \(E\) swings between the two points where the curve meets the line of height \(E\). Heating the solid gives each atom more energy, so the line rises. On the steep side the turning point hardly moves. On the gentle side it moves far out.

Why a warmer solid is largerThe potential energy U of two neighbouring atoms against their separation r. The well is lopsided: steep on the left, where the atoms are pushed together, and gentle on the right, where they are pulled apart. The horizontal line is the energy of the vibrating atom; it swings between the two points where the line meets the curve. Chips raise the energy from cold to warm to hot. The swing widens mostly to the right, so the middle of the swing, marked, moves outward from r0: the mean separation grows.OrU r0 middle: r/r0 = 1.03
Fig 4.1The potential energy \(U\) of two neighbouring atoms against their separation \(r\); the lowest point is at \(r_0\). The line is the energy of the vibrating atom. Choose a chip. As the energy rises, the swing widens mostly to the right, and the middle of the swing moves out from \(r_0\). The energies are exaggerated.

In Fig 4.1 the middle of the swing sits at \(1.03\,r_0\) when cold and moves to \(1.30\,r_0\) when hot. So the average spacing of neighbours grows with temperature. Every pair of neighbours moves apart a little. Added over billions of atoms in a row, the solid becomes measurably longer.

Intuition

Picture a child on a swing hung next to a wall. The wall stops the swing sharply on one side, while on the other side the swing rises freely. Push harder and the swing goes much further on the open side than towards the wall. The middle of its motion moves away from the wall.

CheckpointUnanswered

Suppose the force between two atoms were exactly like an ideal spring, so the energy well was symmetric. What would happen when the solid is heated?

Linear expansion
Maths you need

Linear expansion

A rod of length \(L\) is warmed by a small amount \(\Delta T\). Each small piece of it grows by the same fraction, so the rod grows in proportion to its length. The growth is also in proportion to the rise in temperature. So \(\Delta L = L\alpha\,\Delta T\). The constant \(\alpha\) belongs to the material and is its coefficient of linear expansion.

RememberLinear expansion
\[ \Delta L = L\alpha\,\Delta T, \qquad L' = L(1 + \alpha\,\Delta T), \qquad \alpha = \dfrac{\Delta L}{L\,\Delta T} \]
Holds whena solid rod heated or cooled through a moderate range, so that \(\alpha\,\Delta T \ll 1\); \(\Delta T\) is negative on cooling
Symbols\(L\) length before, \(L'\) length after, \(\Delta L\) change in length, \(\Delta T\) change in temperature, \(\alpha\) coefficient of linear expansion
Units\(\alpha\) in K⁻¹, the same number per °C; dimensions \([\Theta^{-1}]\), since \(\Delta L/L\) is a pure number

The value of \(\alpha\) is small. For steel it is \(1.2 \times 10^{-5}\,\text{K}^{-1}\), for brass \(1.9 \times 10^{-5}\), for aluminium \(2.4 \times 10^{-5}\) and for ordinary glass \(9 \times 10^{-6}\). The alloy invar has only about \(1 \times 10^{-6}\). A steel rod warmed by \(45\,\text{K}\) grows by \(1.2 \times 10^{-5} \times 45 = 5.4 \times 10^{-4}\) of its length, which is \(0.054\,\%\). A long rod and a short rod grow by the same percentage.

The rail and its gap

Now the rails of the phenomenon. Each steel rail is \(13\,\text{m}\) long, with \(\alpha = 1.2 \times 10^{-5}\,\text{K}^{-1}\). From the cold morning when the track was laid to a Rajasthan summer afternoon, the rails may warm by \(45\,\text{K}\). Then each rail grows by \(\Delta L = 13 \times 1.2 \times 10^{-5} \times 45\,\text{m}\). That is \(7.0 \times 10^{-3}\,\text{m}\), or \(7.0\,\text{mm}\).

The gap between two railsA steel rail 13 metres long between two neighbours, with the gaps left when the track was laid. A slider warms the track by up to 45 kelvin, and the rails turn from pale to red. Each rail grows at both ends, so each gap closes by the growth of one whole rail. The gap of 7.0 millimetres closes exactly at 45 kelvin. The gaps and the growth are drawn 200 times larger than the rails. 13 m rail ΔT = 20 K: each rail grows 3.1 mm gap = 3.9 mm
SimA \(13\,\text{m}\) steel rail between two neighbours. Move the slider to warm the track by up to \(45\,\text{K}\). Each rail grows at both ends, so each gap closes by the growth of one whole rail, and the \(7.0\,\text{mm}\) gap closes exactly at \(45\,\text{K}\). The gaps and the growth are drawn 200 times larger than the rails.

Watch one gap in the sim above. The rail on its left pushes its right end in by half its growth, \(3.5\,\text{mm}\) at \(45\,\text{K}\). The rail on its right pushes its left end in by the same amount. So the gap closes by the growth of one whole rail, and a gap of \(7.0\,\text{mm}\) is just enough. Lesson 6 shows what happens when no gap is left.

ExampleA bridge that breathes

A steel span is \(457\,\text{m}\) long, the length of the main span of the Howrah Bridge in Kolkata. Between a winter night and a summer afternoon its temperature rises by \(25\,\text{K}\). By how much does it lengthen? Take \(\alpha = 1.2 \times 10^{-5}\,\text{K}^{-1}\).

Try it on paper first. The solution is one tap away when you are ready.
Checkpoint · numericUnanswered

An aluminium rod is \(2.0\,\text{m}\) long. It is warmed by \(50\,\text{K}\). Take \(\alpha = 2.4 \times 10^{-5}\,\text{K}^{-1}\). By how many millimetres does it lengthen?

mm± 2 %
Checkpoint · numericUnanswered

A steel rod (\(\alpha = 1.2 \times 10^{-5}\,\text{K}^{-1}\)) is longer than an aluminium rod (\(\alpha = 2.4 \times 10^{-5}\,\text{K}^{-1}\)) by \(12\,\text{cm}\) at every temperature. How long is the steel rod, in cm?

cm± 2 %
CheckpointUnanswered

A copper wire \(1\,\text{m}\) long and a copper wire \(10\,\text{m}\) long are warmed by the same \(40\,\text{K}\). Which statement is correct?

Area and volume expansion
Maths you need

Area and volume

Most solids are isotropic: they expand by the same fraction in every direction. Take a square plate of side \(a\) and warm it by \(\Delta T\). Each side becomes \(a(1 + \alpha\,\Delta T)\). The area grows by a fraction \(\beta\,\Delta T\), where \(\beta\) is the coefficient of area expansion.

A square plate grows by two strips and a cornerA square plate of side a is heated and each side grows by Δa, which equals a alpha delta T. The new area is the old square plus two strips, each a by Δa, plus a tiny corner square, Δa by Δa. The strips give the fractional change 2 alpha delta T; the corner is the square of a very small number and is dropped. The growth is drawn many times larger than it is.a × a a × Δa a × Δa (Δa)², dropped a Δa
Fig 4.2A square plate of side \(a\) grows by \(\Delta a = a\alpha\,\Delta T\) along each side. The new area is the old square, two strips each \(a \times \Delta a\), and a tiny corner \((\Delta a)^2\). The growth is drawn many times larger than it is.
Deriving \(\beta = 2\alpha, \qquad \gamma = 3\alpha\) step 1 of 4
1

\[ A' = a^2(1 + \alpha\,\Delta T)^2 = a^2\left(1 + 2\alpha\,\Delta T + \alpha^2\,\Delta T^2\right) \]

Why. each side becomes \(a(1 + \alpha\,\Delta T)\), and the area is the side squared. In Fig 4.2 the three terms are the old square, the two strips and the corner.

RememberArea and volume expansion
\[ \Delta A = A\beta\,\Delta T, \qquad \Delta V = V\gamma\,\Delta T, \qquad \beta = 2\alpha, \quad \gamma = 3\alpha \]
Holds whenan isotropic solid with \(\alpha\,\Delta T \ll 1\); for a liquid only \(\gamma\) has a meaning
Symbols\(A\), \(V\) area and volume before, \(\Delta A\), \(\Delta V\) their changes, \(\beta\) coefficient of area expansion, \(\gamma\) coefficient of volume expansion, \(\alpha\) coefficient of linear expansion
Units\(\alpha\), \(\beta\), \(\gamma\) in K⁻¹

The coefficient of volume expansion \(\gamma\) is the one that matters most for liquids and gases. A liquid has no shape of its own, so it has no length to expand. It has only a volume, and only \(\gamma\) describes it.

Deeper

A crystal such as calcite is not isotropic: it expands by different fractions along its three axes, with coefficients \(\alpha_x\), \(\alpha_y\) and \(\alpha_z\). Multiply the three new edges of a box and drop the products of small terms. The result is \(\gamma = \alpha_x + \alpha_y + \alpha_z\), and a face in the \(xy\) plane has \(\beta = \alpha_x + \alpha_y\). For an isotropic solid all three are \(\alpha\), and \(\gamma = 3\alpha\) again.

ExampleA steel sheet and a copper cube

(a) A steel sheet (\(\alpha = 1.2 \times 10^{-5}\,\text{K}^{-1}\)) has an area of \(2.0\,\text{m}^2\). Find the increase in its area, in cm², when it warms by \(50\,\text{K}\). (b) A copper cube (\(\alpha = 1.7 \times 10^{-5}\,\text{K}^{-1}\)) has edges of \(10\,\text{cm}\). Find the increase in its volume when it is heated by \(100\,\text{K}\).

Try it on paper first. The solution is one tap away when you are ready.
CheckpointUnanswered

A metal ball is heated, and its diameter grows by \(0.1\,\%\). By what percentage does its volume grow?

Holes expand too
Predict firstLocked

A steel plate has a round hole in the middle. The plate is heated evenly. What happens to the hole?

A heated plate with a holeA square steel plate with a round hole, drawn cold and heated; the dashed outlines mark the cold plate and the cold hole. When the plate is heated, every length in it grows by the same fraction, the width of the hole included, so the hole becomes larger. The third chip fills the hole with a disc of the same steel: the disc grows by the same fraction and still fits exactly. The growth is drawn many times larger than it is. cold

The chips show why. Heating makes every distance between atoms grow by the same fraction, as in a photographic enlargement. The distance across the hole is one of those distances. Imagine the hole filled with a disc of the same steel. The disc would grow with the plate and still fit exactly. So the hole grows as if it were made of the material around it.

The same holds for a cavity. The inside of a glass flask grows as if the cavity were solid glass. A flask that holds \(1000\,\text{cm}^3\) at \(20\,°\text{C}\) holds \(1000 \times 3 \times 9 \times 10^{-6} \times 100 = 2.7\,\text{cm}^3\) more at \(120\,°\text{C}\). Lesson 5 needs this result.

Shrink-fitting

A village blacksmith fits an iron tyre on a wooden cart wheel by using a hole that grows. The tyre is made slightly smaller than the wheel. He heats it in a fire until its inner width grows past that of the wheel, drops it on and pours water over it. The tyre shrinks as it cools and grips the wheel with great force. Steel rims of railway wheels are fitted the same way.

ExampleFitting an iron tyre

An iron tyre has an inner diameter of \(100.00\,\text{cm}\) at \(25\,°\text{C}\). It must slide onto a wheel of diameter \(100.12\,\text{cm}\). To what temperature must it be heated? Take \(\alpha = 1.2 \times 10^{-5}\,\text{K}^{-1}\).

Reveal one step at a time and finish the rest yourself.
Checkpoint · numericUnanswered

A steel plate has a hole \(4.0\,\text{cm}\) across. The plate is heated by \(200\,\text{K}\). Take \(\alpha = 1.2 \times 10^{-5}\,\text{K}^{-1}\). By how many millimetres does the diameter of the hole change?

mm± 2 %
CheckpointUnanswered

A glass jar (\(\alpha = 9 \times 10^{-6}\,\text{K}^{-1}\)) has a tight aluminium lid (\(\alpha = 2.4 \times 10^{-5}\,\text{K}^{-1}\)). The top of the jar is held under hot water. What happens to the grip of the lid?

Story · Pieter van Musschenbroek, 1731
Measuring a growth too small to see

In 1731 the Dutch professor Pieter van Musschenbroek built an instrument to measure how much a metal rod lengthens when heated. One end of the rod was fixed, and its free end turned a train of levers and gears that moved a pointer across a dial. A growth far thinner than a hair became a visible swing of the pointer. He called the instrument a pyrometer, and with it he compared how much iron, copper and tin expand.

In the world
The teeth across a flyover

Drive over a long flyover in Mumbai or Delhi and the car thumps across a strip of interlocking steel teeth every few hundred metres. These are expansion joints. The concrete deck lengthens on a hot afternoon and shortens at night, and the teeth slide into each other to take up the change. Without them the deck would push against its supports and crack.

Exam traps
  1. Using \(\beta = \alpha\) or \(\gamma = \alpha\) for an area or a volume.
    For an isotropic solid \(\beta = 2\alpha\) and \(\gamma = 3\alpha\): an area has two lengths, a volume three.
  2. Thinking a hole shrinks when the plate around it is heated.
    Every distance grows by the same fraction. The hole grows as if it were filled with the same material.
  3. Leaving \(L\) in centimetres and \(\Delta L\) in metres.
    \(\Delta L/L = \alpha\,\Delta T\) is a pure number, so \(\Delta L\) comes out in the unit of \(L\).
  4. Making a rail gap half the growth of a rail.
    Each gap is closed from both sides, so it must equal the full growth of one rail.