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Fission and the Reactor

14 min read3 ideas7 checks3 figures to playBy Asheshanand Acharya
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Nuclear fission

A nucleus that splits

The binding energy curve says that a uranium nucleus would release about 200 MeV if it split. It does not split by itself, or only very rarely. It needs a push: a neutron. A neutron has no charge, so it feels no Coulomb barrier and can drift into the nucleus even when it moves slowly.

Story · Otto Hahn, Fritz Strassmann, Lise Meitner and Otto Frisch, Berlin and Sweden, 1938
Barium where there should be none

In 1938 Otto Hahn and Fritz Strassmann bombarded uranium with neutrons in Berlin. Among the products they found barium, with less than half the charge of uranium. Hahn wrote to his old colleague Lise Meitner, who had fled Germany that summer. Over Christmas in Sweden, she and her nephew Otto Frisch worked it out. The nucleus had split in two, and the pieces must fly apart with about 200 MeV. Frisch borrowed a word from biology for it: fission.

Here is what happens. A slow neutron is captured by a uranium-235 nucleus, which becomes uranium-236 with some extra energy. The new nucleus quivers like a drop of liquid. If it stretches into a dumbbell, the electric repulsion between the two ends pushes them apart. The short-range nuclear force cannot pull them back. The nucleus splits.

A slow neutron splits uranium-235A slow neutron drifts into a uranium-235 nucleus drawn to scale. The nucleus becomes uranium-236, quivers, and splits into two unequal fragments that fly apart in opposite directions, the lighter one faster, with two or three fresh neutrons. The chips show two of the many ways it can split: barium-141, krypton-92 and three neutrons, or xenon-140, strontium-94 and two neutrons. Each fission releases about 200 MeV. U-235 U-235 + n → Ba-141 + Kr-92 + 3n
Fig 5.1Nuclei drawn to scale. A slow neutron enters uranium-235, which becomes uranium-236, quivers and splits. The fragments fly apart with equal and opposite momenta, the lighter one faster, and fresh neutrons leave. The two chips show two of the many ways the nucleus can split.
RememberA typical fission of uranium-235
\[ n + {}^{235}_{92}\text{U} \to {}^{141}_{56}\text{Ba} + {}^{92}_{36}\text{Kr} + 3n \]
Holds whenone of many possible splits, through the brief compound nucleus uranium-236; on average about 2.5 neutrons come out, and about 200 MeV is released.
Symbols\(n\) neutron; the fragments differ from fission to fission
Unitsmass numbers and atomic numbers balance: \(236 = 141 + 92 + 3\), \(92 = 56 + 36\)

The fragments are not the same every time. Fig 5.1 shows two of the splits: barium-141, krypton-92 and three neutrons, or xenon-140, strontium-94 and two neutrons. Equal halves are rare. The fragments pile up in two humps, one near \(A = 95\) and one near \(A = 139\). A split into two nuclei near \(A = 118\) is hundreds of times less likely. On average about 2.5 neutrons come out.

ExampleThe energy of one fission from the masses

Find the energy released in \(n + {}^{235}\text{U} \to {}^{141}\text{Ba} + {}^{92}\text{Kr} + 3n\). Masses: \({}^{235}\text{U}\) \(235.0439\,\text{u}\), \(n\) \(1.0087\,\text{u}\), \({}^{141}\text{Ba}\) \(140.9144\,\text{u}\), \({}^{92}\text{Kr}\) \(91.9262\,\text{u}\).

Reveal one step at a time and finish the rest yourself.

Most of the energy appears at once as the kinetic energy of the two fragments, about 170 MeV. They are pushed apart by their electric repulsion, then slowed by the surrounding atoms, which heats the fuel. The rest comes out as neutrons, gamma rays and, later, the decays of the fragments. The fragments carry too many neutrons for the line of stability of the last lesson, so they decay towards it.

The energy is enormous for its mass. One kilogram of uranium-235 holds \(\tfrac{1000}{235} \times 6.02 \times 10^{23} = 2.56 \times 10^{24}\) nuclei. At \(200\,\text{MeV} = 3.2 \times 10^{-11}\,\text{J}\) each, full fission gives \(8.2 \times 10^{13}\,\text{J}\). Burning a kilogram of coal gives about \(3 \times 10^{7}\,\text{J}\), nearly three million times less.

Checkpoint · numericUnanswered

In the fission \(n + {}^{235}_{92}\text{U} \to {}^{140}_{54}\text{Xe} + {}^{94}_{38}\text{Sr} + x\,n\), how many neutrons \(x\) are released?

± 0 %
CheckpointUnanswered

Why can a slow neutron split uranium-235, while a slow proton of the same energy cannot even reach the nucleus?

Chain reaction and the multiplication factor
Maths you need

One fission leads to the next

Each fission takes one neutron and gives back two or three. If at least one of those causes another fission, the process keeps itself going. This is a chain reaction. Fissions come in generations: the neutrons of one generation cause the fissions of the next.

definition 5.4
Multiplication factor

The multiplication factor \(k\) of a chain reaction is the number of fissions in one generation divided by the number in the generation before. After \(n\) generations the number per generation is \(N_n = N_0\,k^n\).

Not every neutron causes a fission. Some escape through the surface. Some are caught by nuclei that do not split. So \(k\) is less than the 2.5 neutrons born in each fission, and its value decides everything. With \(k < 1\) the chain dies out; the reactor is subcritical. With \(k = 1\) each generation equals the last; it is critical. With \(k > 1\) the chain grows without limit; it is supercritical.

Fissions per generation for three values of kA bar chart of the number of fissions in each generation of a chain reaction that starts with 10 fissions. Each generation's bar rises in turn. With k = 0.8 the bars shrink, 10, 8, 6, 5, 4, 3: the chain dies out. With k = 1 every bar is 10: a steady chain, as in a working reactor. With k = 1.5 the bars grow, 10, 15, 23, 34, 51, 76: the chain runs away.1234520406080Onfissions in generation n k < 1: the chain dies out
Fig 5.2The number of fissions in each generation of a chain that starts with 10. Choose \(k\) and press play. With \(k = 0.8\) the bars shrink to 3 by generation 5; with \(k = 1\) they stay at 10; with \(k = 1.5\) they reach 76.

Growth that looks small is not. With \(k = 1.01\), only one per cent above critical, the rate grows by \((1.01)^{100} = 2.7\) in 100 generations. It reaches a thousand times the starting rate after \(\ln 1000/\ln 1.01 \approx 690\) generations. In a bomb, with \(k\) near 2, ten generations multiply the rate by \(2^{10} = 1024\). A generation lasts only a small fraction of a second.

Deeper

Why can people control a chain at all, if a generation is so short? About 0.65 per cent of the neutrons from uranium-235 are not released at once. They come out seconds later, from the decay of certain fragments. A reactor is run so that it reaches \(k = 1\) only with the help of these delayed neutrons. That slows every change of power to a pace that control rods can follow.

Critical mass

Neutrons are born throughout a lump of uranium, but they escape through its surface. In a small lump the surface is large compared with the volume, so most neutrons escape before they meet a uranium-235 nucleus, and \(k < 1\). A bigger lump has less surface for its volume, and \(k\) rises. The least mass for which \(k\) reaches 1 is the critical mass. A sphere needs the least, because it has the smallest surface for its volume; a thin sheet loses nearly every neutron through its faces.

CheckpointUnanswered

A working nuclear power reactor is held at which value of \(k\)?

Checkpoint · numericUnanswered

In a chain reaction each fission leads to exactly two more. Starting from one fission, how many fissions happen in generation 10?

± 0 %
The nuclear reactor
Maths you need

Slowing the neutrons down

Fission neutrons leave with about 2 MeV. A uranium-235 nucleus catches slow neutrons hundreds of times more readily than fast ones. So a thermal neutron, slowed until its energy is about that of the surrounding atoms, \(0.025\,\text{eV}\), is the best trigger. Natural uranium is only 0.7 per cent uranium-235. The rest is uranium-238, which fast neutrons rarely split.

A moderator slows neutrons by elastic collisions. The chapter on Collisions found that a body striking an equal body head-on hands over all its energy. One striking a much heavier body bounces back with nearly all of it. A neutron striking a nucleus of mass number \(A\) head-on loses the fraction \(4A/(1 + A)^2\) of its kinetic energy.

For hydrogen, \(A = 1\), the fraction is 1: a proton can stop a neutron in one hit. For deuterium it is 0.89, for carbon 0.28, and for uranium-238 only 0.017. So a good moderator is made of light nuclei: ordinary water, heavy water or graphite. Even in carbon, a neutron needs more than a hundred collisions to become thermal.

Checkpoint · numericUnanswered

A neutron strikes a carbon-12 nucleus at rest, head-on and elastically. What fraction of its kinetic energy does it lose?

± 2 %

The parts of a reactor

A reactor is a chain reaction held at \(k = 1\) while its heat is carried away. Fig 5.3 shows the parts of a thermal reactor, and each part has one job.

The parts of a thermal reactorA schematic reactor, not to scale. A thick concrete shield surrounds a steel vessel full of water. Inside stand the fuel rods of uranium. Control rods hang from above and can be lowered between them. The water slows the neutrons, as the moderator, and carries the heat away, as the coolant. Hot water leaves at the top right for the heat exchanger, where it boils water in a second loop into steam for the turbine, and comes back cooler at the bottom. heat exchanger hot cooler steam to the turbine control rods water concrete shield
Fig 5.3The parts of a thermal reactor, not to scale. The four white fuel rods stand in water, which is both moderator and coolant. Control rods hang from above. Hot water carries the heat to the heat exchanger, which makes steam for the turbine. A thick concrete shield surrounds the core.
  1. Fuel rods hold the uranium, usually as uranium oxide pellets sealed in metal tubes.
  2. The moderator slows the fission neutrons to thermal speeds: ordinary water, heavy water or graphite.
  3. Control rods of cadmium or boron soak up spare neutrons. Pushed in, they lower \(k\); pulled out, they raise it. Dropped fully in, they stop the reactor.
  4. The coolant carries the heat from the core to a heat exchanger, which boils water into steam for the turbine. It is water, heavy water or liquid sodium.
  5. The shield, thick concrete and steel, stops the neutrons and gamma rays from reaching people.

Boron works in a control rod through the reaction of the last lesson: \(n + {}^{10}\text{B} \to {}^{7}\text{Li} + \alpha\). It needs no threshold and no energy to start, so boron-10 swallows slow neutrons very readily. India's pressurised heavy water reactors, such as those at Rawatbhata and Kaiga, use heavy water as the moderator. Heavy water absorbs far fewer neutrons than ordinary water, so they can run on natural uranium.

Checkpoint · select all that applyUnanswered

Which of these statements about the parts of a thermal reactor are correct?

In the world
Kudankulam, Tamil Nadu

The Kudankulam power station stands on the coast of Tirunelveli district. Each of its two running reactors gives 1000 MW of electricity, and more units are being built. They are pressurised water reactors: ordinary water under pressure is both moderator and coolant, and the fuel is enriched to a few per cent uranium-235. About a third of the heat becomes electricity, so each unit makes about 3000 MW of heat. That needs \(9.4 \times 10^{19}\) fissions every second, which use up about 3 kg of uranium-235 a day.

EstimateUnanswered

A reactor produces 1000 MW of heat. Each fission gives \(200\,\text{MeV} = 3.2 \times 10^{-11}\,\text{J}\). Estimate the mass of uranium-235 it uses in one day, in kilograms.

kgrough value is enough
Exam traps
  1. Thinking fast neutrons are best for splitting uranium-235.
    U-235 captures slow, thermal neutrons hundreds of times more readily. The moderator slows them.
  2. Believing a heavy moderator slows neutrons best.
    A neutron loses most energy to a nucleus of its own mass. Light nuclei, such as hydrogen and carbon, make moderators.
  3. Equating \(k\) with the number of neutrons from each fission.
    \(k\) counts fissions per generation. Neutrons that escape or are absorbed do not count.
  4. Saying control rods slow the neutrons down.
    Control rods absorb neutrons. Slowing them is the moderator's job.