The time to halve
The decay constant is exact but hard to picture. A more natural measure is the time a sample takes to fall to half. This is the half-life \(T_{1/2}\). Because an exponential falls by the same fraction in every equal interval, the half-life does not depend on how much there was to start with. In each half-life the sample halves again: to \(\tfrac12\), \(\tfrac14\), \(\tfrac18\) of the start, in equal steps of time.
Fig 4.1 shows the steps for a technetium-99m dose, whose half-life is \(6\,\text{h}\). The first \(400\,\text{MBq}\) go in six hours, the next \(200\,\text{MBq}\) in the next six, then \(100\,\text{MBq}\). The amount lost in each step shrinks, but the time for each halving never changes.
To link the half-life to \(\lambda\), put \(N = N_0/2\) at \(t = T_{1/2}\) into the decay law. Fill in the missing step.
\[ \dfrac{N_0}{2} = N_0\,e^{-\lambda T_{1/2}} \]
Why. at one half-life, half the nuclei are left.
?
Your turn. cancel \(N_0\) and turn the equation over. Which line is it?
\[ \lambda T_{1/2} = \ln 2 \]
Why. take the natural logarithm of both sides.
\[ T_{1/2} = \dfrac{\ln 2}{\lambda} = \dfrac{0.693}{\lambda} \]
Read it. divide by \(\lambda\); \(\ln 2 = 0.693\).
A nuclide has a half-life of \(6.93\,\text{h}\). Find its decay constant, and the fraction of a sample left after \(13.86\,\text{h}\).
\(\lambda = 0.693/T_{1/2} = 0.693/6.93 = 0.1\) per hour.
\(13.86\,\text{h}\) is exactly two half-lives, so the fraction left is \(\tfrac12 \times \tfrac12 = \tfrac14\). The decay law agrees: \(e^{-0.1 \times 13.86} = e^{-1.386} = 0.25\).
Values used: \(\ln 2 = 0.693\).
Technetium-99m has a half-life of \(6.0\,\text{h}\). Find its decay constant, in per hour. Take \(\ln 2 = 0.693\).
Samples P and Q start with the same number of nuclei. P has a half-life of \(1\,\text{h}\) and Q of \(2\,\text{h}\). At the start, P's activity is twice Q's. What is the ratio of P's activity to Q's after \(2\,\text{h}\)?
How long does a nucleus live, on average?
Some nuclei of a sample decay in the first second, and a few survive for many half-lives. The average lifetime of all of them is the mean life \(\tau\). To find it, count the nuclei that decay between \(t\) and \(t + dt\). There are \(\lambda N_0 e^{-\lambda t}\,dt\) of them, and each lived for a time \(t\). Average \(t\) over all \(N_0\) nuclei.
\[ \tau = \dfrac{1}{N_0}\int_0^\infty t\,\lambda N_0 e^{-\lambda t}\,dt \]
Why. add the lifetimes of all the nuclei and divide by their number, \(N_0\).
\[ \tau = \lambda\int_0^\infty t\,e^{-\lambda t}\,dt \]
Why. \(N_0\) cancels.
\[ \int_0^\infty t\,e^{-\lambda t}\,dt = \dfrac{1}{\lambda^2} \]
Why. integrate by parts; the result is a standard integral.
\[ \tau = \dfrac{1}{\lambda} \]
Read it. multiply by \(\lambda\).
The mean life is longer than the half-life, \(\tau = T_{1/2}/0.693 = 1.44\,T_{1/2}\). The few nuclei that survive for many half-lives pull the average up. At \(t = \tau\) the decay law gives \(N = N_0e^{-1} = 0.37\,N_0\). So after one mean life about 37 % of the nuclei are left, a little less than the half left after one half-life.
Fig 4.2 shows a second meaning of \(\tau\). The tangent at the start has slope \(-\lambda N_0\), so it reaches zero at \(t = N_0/(\lambda N_0) = 1/\lambda = \tau\). The mean life is the time the sample would take to decay completely if it kept its first rate. The rate falls instead, so the sample outlasts this estimate. The same holds at every point, as the tangent figure of the last lesson showed.
A half-life is the median lifetime: half the nuclei live less than \(T_{1/2}\) and half live longer. A mean life is the average. A few very long lives pull the average up, as a few very rich families pull up the average income of a town. So the average, \(\tau\), is larger than the median, \(T_{1/2}\).
A nuclide has a half-life of \(6.93\,\text{h}\). Find its mean life, in hours. Take \(\ln 2 = 0.693\).
What fraction of a radioactive sample is left after one mean life?
Counting in half-lives
Since \(\lambda T_{1/2} = \ln 2\), the decay law can be written with the half-life alone. Put \(\lambda = \ln 2/T_{1/2}\) into \(N = N_0e^{-\lambda t}\). Then \(e^{-\lambda t} = e^{-(t/T_{1/2})\ln 2} = 2^{-t/T_{1/2}}\), so \[ N = N_0\left(\tfrac12\right)^{n}, \qquad n = \dfrac{t}{T_{1/2}} \] Here \(n\) is the number of half-lives that have passed. It need not be a whole number.
After 1 half-life \(\tfrac12\) is left and \(\tfrac12\) has decayed. After 3 half-lives \(\tfrac18\) is left and \(\tfrac78\) has decayed. After 5 half-lives only \(\tfrac1{32}\) is left, and \(\tfrac{31}{32}\) has decayed. For a fraction of a half-life, use the power directly: after \(9\,\text{h}\), 1.5 half-lives of technetium-99m, the dose is \(800 \times 2^{-1.5} = 283\,\text{MBq}\).
A fraction that is not a power of \(\tfrac12\) needs a logarithm. To fall to one tenth, \(e^{\lambda t} = 10\), so \(t = \ln 10/\lambda\). With \(\ln 10 = 2.303\) and \(\lambda = 0.693/T_{1/2}\), this is \(t = (2.303/0.693)\,T_{1/2} = 3.32\,T_{1/2}\). A nuclide with a half-life of 3 days falls to a tenth of its activity in about 10 days.
A hospital treats thyroid patients with iodine-131, half-life 8 days. A used source has an activity of \(3200\,\text{Bq}\). It may be sent for disposal as ordinary waste once its activity is down to \(100\,\text{Bq}\). After how many days is that?
The activity must fall by the factor \(3200/100 = 32\).
\(\left(\tfrac12\right)^n = \dfrac{100}{3200} = \dfrac{1}{32}\).
\(2^5 = 32\), so \(n = 5\) half-lives, and \(t = 5 \times 8 = 40\) days.
The source may be discarded after 40 days. Values used: the half-life of iodine-131, 8 days.
A sample holds \(8 \times 10^{20}\) nuclei of a nuclide with a half-life of 5 days. How many nuclei have decayed after 15 days? Give the answer in units of \(10^{20}\).
A nuclide has a half-life of 3 days. After how many days has its activity fallen to one tenth? Take \(\ln 2 = 0.693\) and \(\ln 10 = 2.303\).
About how many half-lives must pass before only one nucleus in a million of a sample is left?
Twenty-four hours after the morning measurement, the technetium dose of the last lesson is down to \(800/16 = 50\,\text{MBq}\), four half-lives later. The waste of a day's work is therefore harmless within a few days. That is why hospitals prefer a short-lived tracer: it does its work in an afternoon and is gone by the end of the week.
- Thinking the whole sample is gone after two half-lives.Each half-life halves what is left. After two, a quarter remains; after three, an eighth.
- Using \(T_{1/2} = 1/\lambda\).\(1/\lambda\) is the mean life. The half-life is \(0.693/\lambda\), which is shorter.
- Believing half the nuclei are left after one mean life.After one mean life \(1/e\), about 37 %, is left. Half is left after one half-life.
- Applying \(N_0/2^n\) only for whole numbers of half-lives.\(n = t/T_{1/2}\) may be any number: \(2^{-1.5} = 0.354\).